WebMay 8, 2007 · The 2,2,2-trichloroethoxycarbonyl (Troc) group has been successfully used as a protecting group for aminoacridines. Unlike aliphatic amines, deprotection of these aromatic amines yields ... http://may.chem.uh.edu/teach-files/Protecting%20Groups.pdf

Protecting Groups in Peptide Synthesis - Springer Nature

WebProtection of Amino Groups. The reaction of aliphatic and aromatic secondary and tertiary N-tritylamines with lithium powder and a catalytic amount of naphthalene led to reductive detritylation affording the corresponding amines in good yields.The trityl group could selectively be removed in the presence of an allyl or a benzyl group. WebSep 12, 2005 · Finally, there are reports of substituting a more labile protecting group for the N-benzyl. 8, 9 Rawal et al. report displacing the N-benzyl with 2,2,2-trichloroethoxycarbonyl (Troc) and deprotecting with Zn/acetic acid, and Campbell et al. report substituting with β-trimethylsilylethyl chloroformate (Teoc) then deprotecting with tetra-n ... spice drying machine

TROC - Definition by AcronymFinder

WebProtecting Groups Hydroxyl Protection Methyl Ethers Formation: Stability: Cleavage: Adv./Disadv.:Methyl ethers, with the exception of aryl methyl ethers, are often difficult to … WebOct 1, 2005 · The Troc (2,2,2-trichloroethoxycarbonyl) protecting group was efficiently removed under neutral conditions from corresponding protected hydrazines and amines using mischmetal in good to excellent ... WebHerein, we describe some common protecting groups and their general unmasking methods, in order to mask and expose amine, carboxylic acid, alcohol, and thiol functionalities to achieve the synthesis of peptides and related molecules. Based on techniques Trang Thi Nguyen Springer Protocols See more References spice dumpling remix